Dave,
The following is typical of what I have read & found through testing in 30 cc size engines.
"I just finished reading the post on porting the underside of the piston. Some of the post mentioned the benefits of thermal barriers being used on the tops of the pistons. About 10 years ago a customer with deep pockets wanted me to develop a single cylinder engine for 250cc shifter kart. He was an older gentleman that used to drive top fuel dragsters. He was not too concerned about his driving abilities in the corners, he just wanted to pass people on the straight-aways. Initially we developed his CR 250 Honda engine on gasoline. We spent 2 or 3 months, went through a lot of cylinders, heads, carbs, ignitions, built around 30 completely different exhaust system with many head pipe and midsection adjustments on each system to get the desired shape of power curve. Our quest for more power continued until the piston crown reached its thermal limits. He petitioned the local club to let him run methanol. They agreed to let him run methanol with a slight weight penalty. He came back to me and now he wanted to develop the engine to run on methanol. We started over, developing new cylinders, heads, exhaust etc. We continued to develop the engine until we again reached the thermal limits of the piston crown. We pushed the power limits about 12 to 15 HP higher on methanol until we reached the same thermal limits of the piston crown.
We decided to try some insulating barriers applied to the piston crown. We sent off a batch of pistons to some place in New York. I think one of the barriers was almost undetectable as far as color and the other one was on off white to gray look. I made the necessary adjustment in the piston to head clearance to allow for the thickness of the coating and checked and set the clearance volumes to the same specs we had on the uncoated pistons. I think the thickness was about .002 to .003 in. thick.
We install one of the new pistons and continued our dyno testing on the engine. We had instant detonation problems as soon as the engine came up to temp under a sustained hard load. We made many adjustments to carburetion, ignition timing, different spark plug designs, combustion chamber designs, stinger diameter changes and any thing else I could think of that would help eliminate the detonation problem without throwing away the power we had worked so long for. I changed to the other piston. I think that one had the white to gray colored coating on the piston crown. The detonation problem was a little more severe. We put a stock uncoated piston back in the engine and the detonation problems immediately went away.
The under side of the coated pistons did not show any signs of overheating where the stock pistons that were operating on the thermal limits had stalactites of ash clinging to the bottom side of the piston. I went back to some of my thermodynamics text books and hand books on heat transfer and properties of good insulators and did a quick study: some of the characteristic themes of a good insulator was… 1) very little energy is transferred through the insulator….2) the surface temperature of the insulator on the heat source side of the insulator is very close to the same temperature as the heat source. 3) The temperature on the other side of the insulator is very close to the temperature of the medium or heat sink.
I came to the conclusion that the thermal barrier was reducing heat transfer into the piston crown. ( I think the underside of the piston reinforced this conclusion) I also believe the surface temperatures of the coating was so high that it was promoting the detonation, even though the piston crown was much cooler than the uncoated pistons crowns that did not promote detonation.
I am sure I am not the first engine developer to encounter the problem. The coating people did not have any explanations. Some of my associates are engineers for some of the aerospace companies that coat all kinds of parts in the high heat side of the gas turbines and jet engines. They say the coatings helps reduce the heat input into the hot parts of the engine, but they do not have to deal with detonation problem that plague high output piston engines. Do these coatings really benefit a piston engine that is developed to the point that the whole top of the piston is on the verge of caving in because of the high thermal load? Should we coat the top of the pistons to help prevent the piston crown from caving in and have the detonation eat up the outer edges of the piston, head and cylinder? Should we run the uncoated pistons that were detonation free but the tops occasionally sag or crack? I welcome your input. What was I missing?"
All I'm asking is why TK found it necessary to coat the piston crowns?
Jim Allen